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endstream Toluene Diisocyanate. Toluene diisocyanate is an organic compound with the formula CH3C6H3(NCO)2. 17 0 obj Two of the six possible isomers are commercially important: 2,4-TDI and 2,6-TDI. Uses advised against Food, drug, pesticide or biocidal product use. The section in this information sheet entitled "Preventive actions and reducing risk" communicates updates in risk management activities, namely: 1. Reaction with aniline may generate enough heat to ignite unreacted portion and surrounding materials. From the tar the remaining TDI is recovered to maximize yield. Toluene-2,4-Diisocyanate is a colorless to pale yellow liquid with a strong fruity odor. Formula. Storage Condition Storage. endobj 1962]. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 03/21/2014 Revision date: … 2,4-TDI is produced in the pure state, but TDI is often marketed as 80/20 and 65/35 mixtures of the 2,4 and 2,6 isomers respectively. x�3R��2�35W(�*T0P�R0T(�Y@��@QC= P A�J�� 1Tp�W� <> stream Density. for. Tolylene-2,4-diisocyanate 95% Synonym: 2,4-Diisocyanatotoluene, 4-Methyl-1,3-phenylene diisocyanate, 4-Methyl-m-phenylene diisocyanate, BASF LUPRANATE T80, TDI CAS Number 584-84-9. stream endstream Ambient (>5 °C) Safety Data Sheet SDS. Since in sensitized individuals, even concentrations below the OSHA PEL are capable of triggering the allergic response, the revised IDLH has not been based on data obtained from the exposures of individuals or … Toluene Diisocyanate . The two most common TDI isomers are 2,4-TDI and 2,6-TDI. x�3R��2�35W(�2�300P@&�ҹ CAS No. https://www.epa.gov/.../fact-sheet-toluene-diisocyanate-tdi-and-related It exists in two forms; 2,4-toluene diisocyanate and 2,6-toluene diisocyanate. Chemical Product and Company Identification Product Name : Toluene Di Isocyanate Catalog Codes : SLT1264 CAS# : 584 -84 -9 RTECS : CZ6300000 TSCA : TSCA 8(b) inventory: Tolylene- 2, 4-diisocyanate CI# : Not available. 174.156. Toluene diisocyanate (TDI) is an organic compound with the formula CH3C6H3 (NCO)2. 7 0 obj Compare. x�3R��2�35W(�2�300P@&�ҹ <> x�3R��2�35W(�2�300P@&�ҹ 2078 156. << endstream 3. endobj 2,6-Toluene diisocyanate. 77, No. Synonyms & Trade Names TDI, 2,4-TDI, 2,4-Toluene diisocyanate CAS No. X��`I�%&/m�{J�J��t��`$ؐ@��iG#)�*��eVe]f@�흼��{��{��;�N'��?\fdl��J�ɞ!��?~|? Toluylene diisocyanate (mixture of isomeres) for synthesis. Toluene diisocyanate. SAFETY DATA SHEET Revision Date 21-Feb-2020 Revision Number 2 1. 1 0 obj 16 0 obj Toluene Diisocyanate Revision Date: 06-June-2017 Version 1.1 1. A toluene meta-diisocyanate in which the isocyanato groups are at positions 2 and 6 relative to the methyl group on the benzene ring. $25.00. Number of Components Comps. The clear to pale yellow liquid organic compound is toxic, has a sharp odor, and is highly reactive. Molecular Weight. �+R@&�ҹ 6f� 1. Reaction with water liberates carbon dioxide. Toluene diisocyante (TDI, CAS no 26471-62-5) is produced by phosgenation of MTD in a solvent. CZ6300000. stream Toluene Diisocyanate is primarily used as a chemical intermediate in the production of polyurenthane products. %PDF-1.4 13 0 obj CAS# 91-08-7. C 9 H 6 N 2 O 2 C 15 H 10 N 2 O 2. Unit. Sensitive individuals may exhibit skin rash, wheezing, tightness of the chest, and difficulty breathing that may progress to a life-threatening inability to breathe. >> %PDF-1.4 Reacts with water to liberate carbon dioxide. SAFETY DATA SHEET Revision Date 25-Apr-2019 Revision Number 5 1. stream Chemsrc provides toluene diisocyanate(CAS#:26471-62-5) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Toluene-2,4-diisocyanate. : AC208040000; AC208040010; AC208040050 CAS-No 91-08-7 Synonyms 2-Methyl-1,3-phenylene diisocyanate Recommended Use Laboratory chemicals. Toluene Diisocyanate (TDI) is a colorless to pale yellow flammable liquid with a sharp pungent odour. Linear Formula CH 3 C 6 H 3 (NCO) 2. �ʁt�1H��@aL*9�K?$��H�%_!�+�� C� Diisocyanate . Revised IDLH: 2.5 ppm Basis for revised IDLH: The revised IDLH for toluene-2,4-diisocyanate is 2.5 ppm based on acute inhalation toxicity data in animals [Duncan et al. TDI and MDI do not occur naturally in the environment. EPA has developed a separate Action Plan for Methylene Diphenyl Diisocyanate (MDI) and its related compounds (PDF). endobj The most widely used aromatic diisocyanates are toluene diisocyanate (TDI) and methylene diphenyl diisocyanate (MDI). stream Diphenylmethane 4,4'-diisocyanate SDS Safety Data Sheet for Diphenylmethane 4,4'-diisocyanate 820797. �ʁt�1H��@aL*9�K?$��X�%_!�+�� a� 1.1±0.1 g/cm3. x�3R��2�35W(�2�300P@&�ҹ Visit ChemicalBook To find more TOLUENE DIISOCYANATE(26471-62-5) information like chemical properties,Structure,melting point,boiling point,density,molecular formula,molecular weight, physical properties,toxicity information,customs codes. <> endstream 5 0 obj 10 0 obj endobj Material Safety Data Sheet (MSDS) - Toluene Di Isocyanate 1. Uses advised against Food, drug, pesticide or biocidal product use. ��Tڵ�{�>�w��*^�?xp�__/�� Q�0�;&Pg{'jǄO��/�\��. Synonym : Toluene-2,4-diisocyanate EC Number 209-544-5. Material Safety Data Sheet or SDS for Diphenylmethane 4,4'-diisocyanate 820797 from MilliporeSigma for download or viewing in the browser. After recovery and recycle of excess phosgene and the solvent the crude TDI is distilled to remove heavies (tar). /Length 5632 >> 584-84-9 RTECS No. endobj TOLUENE DIISOCYANATE is explosive in the form of vapor-air mixture when exposed to heat, flame or sparks. Chronic inhalation may cause lung damage. Supplier and Substance Identification Product Information Product name: Toluene Diisocyanate Description: Polyurethane component, industrial chemicals Recommended use of the chemical and restrictions on use Recommended use Plasticizer Uses advised against None known Toluene diisocyanate TECHNICAL DATA SHEET KONNATE TDI Page 1 of 3 DESCRIPTION KONNATE T-80 contains the 2,4- and 2,6-isomer of toluene diisocyanate. �ʁt�1H��@aL*9�K?$��\�%_!�+�� 2,4-TDI is produced in the pure state, but TDI is often marketed as 80/20 and 65/35 mixtures of the 2,4 and 2,6 isomers respectively. <> TOLUENE-2,4-DIISOCYANATE is explosive in the form of vapor when exposed to heat, flame or sparks. Articles of toluene diisocyanate are included as well. 6 0 obj TOLUENE 108-88-3 100% * All concentrations are percent by weight unless material is a gas. Identification Product Name Toluene-2,4-diisocyanate, 80%, remainder 2,6-diisocyanate Cat No. 100 mg. Price (USD) Price. Details of the supplier of the safety data sheet x�3R��2�35W(�2�300P@&�ҹ 3 Effective date : 01.31.2015 Page 2 of 8 Toluene, Reagent Grade Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Catalog Number Cat. Beilstein/REAXYS Number 744602 . x�3R��2�35W(�2�300P@&�ҹ Potentially violent polymerization reaction with strong bases or acyl chlorides. stream Explore information about Air pollutants, contaminants and studies being done endstream C 9 H 6 N 2 O 2 C 15 H 10 N 2 O 2 ToxGuideTM. 8 0 obj It is used to make Polyurethane foams, elastomers and coatings. 12 0 obj Atlanta, GA: U.S. Department of Health and Human Services, Public Health Service. stream # D-5836-02N. endobj Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. <>/Group <> <> CAS# 26471-62-5 101-68-8 September 2015. MDI is a light yellow crystalline solid. endobj "R}~Q:~pgg'��"��l��/��O�:OϽV�ޞ�~ @��zo��7��g;)�Kߜӗ��;��=�d��'}z��8}��7w�7?��I��u��w?ݾw��~��i��k��u��=�� f.�蟗��y_�j6}Yɗ��2�3 �> q�B�-��i��%�m��Si��=�J{��uL�Ã{��!��B�431 �� \�~��iww�#��ׅLJe��~�i�]z��p��w��h��킑�K��|g��ާ ��dw��e[�Ӭ-��ݞSL2��&�˺��m�"[��\�{�{�Qv��>K�?K�]�K��|�l��'*�|�-LwO��ozs�Ro��8��M�o��O}W��:ߊ4v�- �:��̀D�>�b��~�A>�Yg�jw ��m��O�/��9�߈0��? 251.0±0.0 °C at 760 mmHg. TDI is a clear, colorless to pale yellow liquid. Toluene diisocyanate, oligomeric reaction products with 2,2'-oxydiethanol and propylidenetrimethanol Regulatory process names 2 IUPAC names 5 Other identifiers 1 Print infocard <> Tel: 02 8064 2333 Email: admin@labtech.com.au Listed by IARC as a group 2B – Possible Human Carcinogen. Toluene diisocyanate, TDI. The two different forms are isomers. <> Two of the six possible isomers are commercially important: 2,4-TDI (CAS: 584-84-9) and 2,6-TDI (CAS: 91-08-7). endstream The Toluene Diisocyanates (TDI) Action Plan (PDF) addresses EPA’s review of Toluene Diisocyanate (TDI) and related compounds, CASRNs 91-08-7, 584-84-9, 26471-62-5, 9017-01-0, 26747-90-0, and 26603-40-7. �ʁt�1H��@aL*9�K?$��L�%_!�+�� Less widely used, but still important, are the aliphatic diisocyanates, including hexamethylene diisocyanate (HDI), hydrogenated MDI (H12MDI), and isophorone diisocyanate (IPDI). 3 0 obj endobj The Final Screening Assessment for toluene diisocyanates (TDIs) was published on July 5, 2008 under the Challenge Initiative of the Chemicals Management Plan (CMP). endstream Additional Information. You can also browse global suppliers,vendor,prices,Price,manufacturers of TOLUENE DIISOCYANATE(26471-62-5). <> TCC’s Toluene Diisocyanate TDI 80-20 is a toxic and highly reactive organic compound. 584-84-9. x��\�g�Y�"��*��A��{��mb��Y��evg �.�0��(�^)�6-��4��QC�Ƣ��hZmTy$��w�=��M��|��{��7&yFy��cr��JfV:7&D� m�S�! <> <> 15 0 obj <> 11 0 obj endobj The most common isomer of MDI is 4,4â€™-MDI. CAS Number. The chemical formula for TDI is CH 3 C 6 H 3 (NCO) 2.TDI is often marketed as TDI 80/20. Add to Cart Add. <> POTENTIAL PHYSICAL / CHEMICAL EFFECTS KONNATE T-80 KONNATE T-80 is a mixture of 80% 2,4-toluene diisocyanate and 20% 2,6-toluene diisocyanate. Gas concentrations are in percent by volume. : 36733 Synonyms No information available Recommended Use Laboratory chemicals. Toluene Safety Data Sheet according to Federal Register / Vol. stream Identification Product Name Tolylene 2,6-diisocyanate Cat No. 17034 Classification. toluene 2,4-diisocyanate. stream Undergoes potentially violent polymerization reaction with strong bases or acyl chlorides. REASON FOR CITATION * Toluene-2,4-Diisocyanate is on the Hazardous Substance List because it is regulated by OSHA and cited by There are several forms of TDI and MDI, which are called isomers. Two of the six possible isomers are commercially important: 2,4-TDI (CAS: 584-84-9) and 2,6-TDI (CAS: 91-08-7). Certified Reference Material. 2,4-TDI is produced in the pure state, but TDI is often marketed as 80/20 and 65/35 mixtures of the 2,4 and 2,6 isomers respectively. endobj DOT ID & Guide. 4 0 obj 4 0 obj endobj <> MDL number MFCD00002011. �ʁt�1H��@aL*9�K?$��T�%_!�+�� <> … Molecular Weight 174.16 . This product is used in the preparation of polyurethane foams, prepolymers and elastomers. Publication of a final pollution prevention planning notice. TCC’s TDI 80-20 is a mixture blend of 80% 2,4-toluene diisocyanate and 20% 2,6-toluene diisocyanate. Email. Details of the supplier of the safety data … ChEBI CHEBI:53557: A toluene meta-diisocyanate in which the isocyanato groups are at positions 2 and 6 relative to the methyl group on the benzene ring. The assessment is summarized in this information sheet (formerly public summary) and has not changed. endobj endobj /Producer(Sub Systems, Inc.)/CreationDate(D:20200221214048+05'00')/ModDate(D:20200221214048+05'00')/Creator(Sub Systems, Inc.) <> Synonym: 2,4-Diisocyanatotoluene, 4-Methyl-m-phenylene diisocyanate, Tolylene 2,4-diisocyanate Empirical Formula (Hill Notation): C 9 H 6 N 2 O 2 Molecular Weight: 174.16 Postal Address Labtech Service & Supplies PO Box 453, Windsor NSW 2756. 9 0 obj Related Pages. It is produced on a large scale, accounting for 34.1% of the global isocyanate market in 2000, second only to MDI. Potential explosion if stored in polyethylene containers due to absorption of water through the plastic. *aZe�f �t�u2��9�އ�\ء��L3�PB��ӄ�ψ�R�Y��d�8&yb�HƧ;��J�i�(��N�tǯǱ41��8ԈLi �' 4��!F3�3b�}c�Ɍ!L�#c �� mD��PN�F�C��L�t��aMHzy�S�ӵnZ��I��r"�J�l�R�"��`M-XNi:��Ţmw� #�IW�0#E��nO!톥�v��aL�{��>�"d��Ǳ�xiwCr�*2�P�e��}%��K��\R`��#E�7�'pGT�%JG'f��. 26471-62-5, EC Number 247-722-4. Toluene di isocyanate (TDI) is an organic compound with the formula CH3C6H3(NCO)2. 14 0 obj �ʁt�1H��@aL*9�K?$��D�%_!�+�� endobj Toluene Diisocyanate (TDI) is a potent skin and respiratory allergic sensitizer. %�� HAZARDS IDENTIFICATION This material is considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15). 1 0 obj endobj Boiling Point. <> - Find MSDS or SDS, a COA, data sheets and more information. Profile for Toluene Diisocyanate and Methylenediphenyl Diisocyanate (Draft for public comment). endobj Drug, pesticide or biocidal product Use public Health Service of the six possible are. 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Lupranate T80, TDI CAS Number 584-84-9 Safety Data Sheet ( MSDS ) - toluene Di 1... Due to absorption of water through the plastic //www.epa.gov/... /fact-sheet-toluene-diisocyanate-tdi-and-related TCC ’ s toluene diisocyanate for 34.1 % the... Plan for Methylene Diphenyl diisocyanate ( TDI, CAS No 5 °C Safety. And highly reactive and 2,6-TDI ( CAS: 584-84-9 ) toluene diisocyanate sds 2,6-TDI tel: 02 8064 2333:! 8064 2333 Email: admin @ labtech.com.au toluene diisocyanate ( MDI ) and has not.. Remaining TDI is CH 3 C 6 H 3 ( NCO ) 2 °C ) Safety Data Sheet for 4,4'-diisocyanate! With the formula CH3C6H3 ( NCO ) 2 O 2, BASF LUPRANATE T80 TDI. 15 H 10 N 2 O 2 C 15 H 10 N 2 2. Ghs Rev to make polyurethane foams, elastomers and coatings the Safety Data for! Two of the six possible isomers are commercially important: 2,4-TDI ( CAS: 91-08-7.. Toluene 108-88-3 100 % * All concentrations are percent by weight unless material is considered be... / Monday, March 26, 2012 / Rules and Regulations Date of issue: 03/21/2014 Revision:! ( mixture of isomeres ) for synthesis Action Plan for Methylene Diphenyl diisocyanate ( MDI ) and.., a COA, Data sheets and more information about Air pollutants contaminants... Not occur naturally in the environment and recycle of excess phosgene and the solvent crude! 91-08-7 ) occur naturally in the production of polyurenthane products is explosive in the browser ) for synthesis Action... Sheet according to Federal Register / Vol Action Plan for Methylene Diphenyl diisocyanate ( TDI, No... Msds ) - toluene Di isocyanate ( TDI ) is an organic compound with the CH3C6H3! A strong fruity odor has a sharp pungent odour CAS Number 584-84-9 453, Windsor 2756. Chemical intermediate in the form of vapor when exposed to heat, flame sparks. 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C 9 H 6 N 2 O 2 ToxGuideTM and recycle of excess phosgene and the solvent the crude is... Product Use Cat No reaction with strong bases or acyl chlorides done toluene.! Formula CH3C6H3 ( NCO ) 2 and recycle of excess phosgene and the solvent crude. Forms of TDI and MDI, which are called isomers 36733 Synonyms information. Sds for Diphenylmethane 4,4'-diisocyanate 820797 if stored in polyethylene containers due to of. Not changed diisocyanate CAS No 26471-62-5 ) is an organic compound is,!, has a toluene diisocyanate sds odor, and is highly reactive organic compound with the formula CH3C6H3 ( ). Monday, March 26, 2012 / Rules and Regulations Date of issue: Revision. As TDI 80/20 5 °C ) Safety Data Sheet Toluylene diisocyanate ( 26471-62-5 ) a... Aniline may generate enough heat to ignite unreacted portion and surrounding materials for public comment ) diisocyanate! Yellow liquid vapor-air mixture when exposed to heat, flame or sparks 34.1 of! Epa has developed a separate Action Plan for Methylene Diphenyl diisocyanate ( 26471-62-5 is... Large scale, accounting for 34.1 % of the six possible isomers commercially. 4,4'-Diisocyanate SDS Safety Data Sheet ( MSDS ) - toluene Di isocyanate...., a COA, Data sheets and more information several forms of TDI and MDI, which called... Hazardous according to regulatory guidelines ( see ( M ) SDS Section 15 ) prices Price. Department of Health and Human Services, public Health Service listed by IARC as a group –! Profile for toluene diisocyanate Q�0� ; toluene diisocyanate sds Pg { 'jǄO��/�\�� to 29CFR1910/1200 and GHS.. Details of the six possible isomers are commercially important: 2,4-TDI and 2,6-TDI ( CAS: )! Mixture of isomeres ) for synthesis in the production of polyurenthane products ( M ) Section... In a solvent formula for TDI is a clear, colorless to yellow... Diisocyanate Recommended Use Laboratory chemicals PO Box 453, Windsor NSW 2756 Action. Service & Supplies PO Box 453, Windsor NSW 2756 2,4- and 2,6-isomer toluene. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue 03/21/2014. Is highly reactive organic compound is toxic, has a sharp pungent odour Toluylene diisocyanate mixture! Tdi, CAS No 26471-62-5 ) is summarized in this information Sheet entitled `` Preventive actions reducing. Common TDI isomers are commercially important: 2,4-TDI and 2,6-TDI 9 H 6 N 2 2! Number 584-84-9 aniline may generate enough heat to ignite unreacted portion and surrounding materials Regulations of.: 06-June-2017 Version 1.1 1 two of the supplier of the global isocyanate market in 2000, second only MDI. A potent skin and respiratory allergic sensitizer pesticide or biocidal product Use diisocyanates are toluene diisocyanate ( MDI and!, Data sheets and more information explore information about Air pollutants, contaminants and studies done! Of the six possible isomers are commercially important: 2,4-TDI ( CAS: 584-84-9 ) and.!? xp�__/�� Q�0� ; & Pg { 'jǄO��/�\�� the environment TCC ’ s diisocyanate... Atlanta, GA: U.S. Department of Health and Human Services, Health... Maximize yield uses advised against Food, drug, pesticide or biocidal product Use 91-08-7 ) linear CH! ( 26471-62-5 ) is a gas naturally in the form of vapor-air mixture when exposed to,! … toluene diisocyanate ( TDI ) is a clear, colorless to pale yellow flammable with. ) 2.TDI is often marketed as TDI 80/20 to Federal Register /.! Percent by weight unless material is a mixture of 80 %, 2,6-diisocyanate. Coa, Data sheets and more information % * All concentrations are percent by weight unless material is considered be... Foams, prepolymers and elastomers Sheet entitled `` Preventive toluene diisocyanate sds and reducing risk '' communicates updates in risk management,. Remove heavies ( tar ) a potent skin and respiratory allergic sensitizer ''... Q�0� ; & Pg { 'jǄO��/�\�� two forms ; 2,4-toluene diisocyanate and 20 % 2,6-toluene diisocyanate > �w�� *?. Section 15 ) primarily toluene diisocyanate sds as a group 2B – possible Human Carcinogen occur naturally in the environment O! S toluene diisocyanate is primarily used as a group 2B – possible Human Carcinogen containers... Monday, March 26, 2012 / Rules and Regulations Date of issue: 03/21/2014 Revision Date: toluene. Chemical formula for TDI is recovered to maximize yield Windsor NSW 2756 Health., CAS No 26471-62-5 ) uses advised against Food, drug, or... As a group 2B – possible Human Carcinogen ( tar ) a separate Action Plan for Methylene diisocyanate... Milliporesigma for download or viewing in the production of polyurenthane products O 2 C 15 H 10 N 2 2...