Dongwei Wei, Hui Li, Cheng Liu, and Baohe Wang . Adipic acid is found to be associated with HMG-CoA lyase deficiency, carnitine-acylcarnitine translocase deficiency, malonyl-Coa decarboxylase deficiency, and medium Chain acyl-CoA dehydrogenase deficiency, which are inborn errors of metabolism. They contain carboxylic groups as their functional group.However, they have different chemical and physical properties as well as different applications. Reacts with oxidizing materials. b. The solubility of adipic acid in water is 1.5 g. per 100 mL at 15?C, and 0.6 g per 100 mL in. Nearly all commercial adipic acid is produced from cyclohexane. Malonic acid (IUPAC systematic name: propanedioic acid) is a dicarboxylic acid with structure CH 2 (COOH) 2.The ionized form of malonic acid, as well as its esters and salts, are known as malonates.For example, diethyl malonate is malonic acid's diethyl ester.The name originates from the Greek word μᾶλον (malon) meaning 'apple'. Measurement and correlation for solubilities of succinic acid, glutaric acid and adipic acid in five organic solvents. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Sile Shi, Mengqi Yan, Bao Tao, Weiping Luo. Adipic Acid × × Purity: >99.0%(GC ... Solubility in Methanol: almost transparency: Properties (reference) Melting Point: 153 °C: Solubility in water: Slightly soluble: Degree of solubility in water : 22 g/l 20 °C: Solubility (very soluble in) Alcohol: Solubility (soluble in) The solubility of adipic acid in methanol, ethanol, propanol, isopropanol, n -butanol, tert -butanol, acetone, 1,4-dioxane, acetic acid, and water was measured within the 0–60°C temperature range. PRODUCT DESCRIPTION. It is slightly soluble in water and soluble in alcohol and acetone. Solubility of succinic acid, glutaric acid and adipic acid in propionic acid + ε-caprolactone + water mixtures: Experimental measurement and thermodynamic modeling. It is freely soluble in alcohol, soluble in acetone, and slightly soluble in water. 1. Weiping Luo, Mengqi Yan, Bao Tao, Sile Shi, Bo Chen. Solubilities of Adipic Acid in Cyclohexanol + Cyclohexanone Mixtures and Cyclohexanone + Cyclohexane Mixtures. Adipic Acid also known as Hexane-1,6-dioic acid is a dibasic acid with the molecular formula C 3 H 8 O 4, CAS 124-04-9.Adipic acid is slightly soluble in water and soluble in alcohol and acetone. It is a white, crystalline compound with a slight acid taste and very faint odor. Biodegradability screening tests indicate that adipic acid is readily biodegradable. Solubility of drug-like molecules in pure organic solvents with the CPA EoS. ADIPIC ACID Prepared at the 53rd JECFA (1999) and published in FNP 52 Add 7 (1999), superseding specifications prepared at the 19th JECFA (1975), published in NMRS 55B (1976) and in FNP 52 (1992). It is not hygroscopic. Adipic Acid. A Unified Thermodynamics Model for Solid–Liquid Equilibrium, Liquid–Liquid Equilibrium, and Vapor–Liquid Equilibrium of Cyclohexane Oxidation Systems: NRTL Model. The compositions of the adipic acid in saturated solution were analyzed by acid−base titration. Adipic acid is also used in baking powders instead of cream of tartar and other foods. Fátima L. Mota, António J. Queimada, Simão P. Pinho, Eugénia A. Macedo. Citations are the number of other articles citing this article, calculated by Crossref and updated daily. ether at the same temperature. Adipic Acid is an acidulant and flavoring agent. The primary hazard is the threat to the environment. If breathing is difficult, give oxygen. This article is cited by Cyclohexane + O2 → cyclohexanol and cyclohexanone 2. cyclohexanol/cyclohexanone + nitric acid+ air → adipic acid + nitrous oxide (The mixture of cyclohexanol and cyclohexanone produced from cyclohexane is commercially called "KA oil", the abbreviation of "Ketone-Alcohol oil".) You have to login with your ACS ID befor you can login with your Mendeley account. White crystalline powder. A sampler for determination of the temperature dependence of the solubility of solids in liquids by the isothermal method was suggested. & Account Managers, For The non-toxic saturated dicarboxylic acid is produced as a white powder. Industrial & Engineering Chemistry Research. Please note: If you switch to a different device, you may be asked to login again with only your ACS ID. Find more information about Crossref citation counts. Fei Wang, Yanyan Li, Zhuoyuan Ning, Chunhua Jiang, and Xunqiu Wang . always use the smallest container you can to make measurements and to do experiments. Other patented processes include those using phenolas feedst… An odd–even effect on solubility of dicarboxylic acids in organic solvents. 151-152 °C (for adipic acid) EU Food Improvement Agents 3.2.3 Solubility Approximately 50 g/100 ml water (20 °C) USE: Adipic acid is a commercially important chemical used during the production of nylon, plastics, lubricants, adhesives, and polyurethane foam. The solubility of adipic acid in methanol, ethanol, propanol, isopropanol, n-butanol, tert-butanol, acetone, 1,4-dioxane, acetic acid, and water was measured within the 0–60°C temperature range. Weiping Luo, Xiuqing Li, Dong Ruan, Dawei Liu, Kaili Xie, Jing Wang, Wei Deng, Qiang Liu, and Zhaoke Chen . Remember the Kd is usually the ratio of. Adipic Acid >99 124-04-9 204-673-3 C 6 H 10 O 4 146.14 g/mol 4. Solubilities of Adipic Acid and Succinic Acid in a Glutaric Acid + Acetone or n-Butanol Mixture. Find more information about Crossref citation counts. Determination of the Adipic Acid Solubility Curve in Acetone by Using ATR-FTIR and Heat Flow Calorimetry. Adipic Acid. Adipic acid is present in some plants and is a chemical in tobacco and tobacco smoke. It is a precursor to diverse industrial products that include polymers, plasticizers, and as a component of many hair and skin conditioners. Function: Buffer; neutralizing agent. Historically, adipic acid was prepared from various fats using oxidation. Inhalation Move casualty to fresh air and keep at rest. It has a slight acidic taste and a very faint odor. Solubility of succinic acid, glutaric acid and adipic acid in propionic acid + ε-caprolactone mixtures and propionic acid + cyclohexanone mixtures: Experimental measurement and thermodynamic modeling. The Effect of Temperature on the Solubility of 11-Cyanoundecanoic Acid in Cyclohexane, n-Hexane, and Water. 607-144-00-9 - REACH : Registration number 01-2119457561-38-0009 It is insoluble in water. Decomposes on heating. Journal of Molecular Liquids 2018, 272, 106-119. It is very soluble in water. It is used heavily in the production of textiles, particularly nylon. COMPOSITION. TECHNICAL DATA. Hui Zhang, Qiuxiang Yin, Zengkun Liu, Junbo Gong, Ying Bao, Meijing Zhang, Hongxun Hao, Baohong Hou, Chuang Xie. Solubility prediction, solvate and cocrystal screening as tools for rational crystal engineering. Solubility of Adipic Acid in Acetone, Chloroform, and Toluene, Research and Development Center for Petrochemical Technology, Tianjin University, Tianjin 300072, P. R. China. https://doi.org/10.1016/j.molliq.2019.111735, https://doi.org/10.1016/j.jct.2019.06.033, https://doi.org/10.1016/j.molliq.2018.09.076, https://doi.org/10.1016/j.jct.2014.05.009, https://doi.org/10.1016/j.snb.2012.11.097, https://doi.org/10.1016/j.fluid.2011.01.014. Adipic acid is a white crystalline solid. expressed as [adipic acid]water/[adipic acid]ether? Its solubility is very low in water and soluble in organic solvents like alcohol and acetone. it is characterized as stable, nonhygroscopic, and slightly soluble, with a water solubility of 1.9 g/100 ml at 20°c. You are currently offline. The C6 straight-chain dicarboxylic acid is slightly soluble in water and soluble in alcohol and acetone. Formula: C 6 H 1 0 O 4 / HOOC(CH 2) 4 COOH Molecular mass: 146.14 Boiling point: 338°C Melting point: 152°C Density: 1.36 g/cm³ Solubility in water, g/100ml at 15°C: 1.4 (moderate) Adipic acid otherwise rarely occurs in nature, but it is known as manufactured E number food additive E355. These metrics are regularly updated to reflect usage leading up to the last few days. The solubility of adipic acid in methanol, ethanol, propanol, isopropanol, n-butanol, tert-butanol, acetone, 1,4-dioxane, acetic acid, and water was measured within the 0–60°C temperature range. Solubility of succinic acid, glutaric acid and adipic acid in propionic acid + ε-caprolactone mixtures and propionic acid + cyclohexanone mixtures: Experimental measurement and thermodynamic modeling. The thermodynamic parameters of solution of adipic acid in the above solvents were calculated. This organic compound is the most important synthetic dicarboxylic acid produced annually. A sampler for determination of the temperature dependence of the solubility of solids in liquids by the isothermal method was suggested. Solubilities of Adipic Acid, Glutaric Acid, and Succinic Acid in Dimethyl Glutarate + Methanol Mixtures: Experimental Measurement and Thermodynamic Modeling. Adipic Acid Chemical Structure Composition. of applications: resins, adhesives, coatings, plastics, paper, plasticizers, detergency . CAS: 124-04-9. High purity Adipic Acid used for the production of nylon 66 and for a wide range . solubilities. Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. a. This probably attributes to the incompatible structures. What is the Kd of adipic acid. SYNONYMS INS No. Some features of the site may not work correctly. Weiping Luo, Dong Ruan, Dawei Liu, Kaili Xie, Xiuqing Li, Wei Deng, and Cancheng Guo . The compositions of the adipic acid in saturated solution were analyzed by acid−base titration. APPEARANCE. Weiping Luo, Mengqi Yan, XiaoXiao Sheng, Bao Tao, Sile Shi, Wei Deng, Weijun Yang. From an industrial perspective, it is the most important dicarboxylic acid: about 2.5 billion kilograms of this white crystalline powder are produced annually, mainly as a precursor for the production of nylon. Measurement and Correlation for Solubilities of Adipic Acid in Acetic Acid + ε-Caprolactone Mixtures and Cyclohexanone + ε-Caprolactone Mixtures. it has a ph of 2.86 at 0.6% usage level at 25°c. You’ve supercharged your research process with ACS and Mendeley! Measuring the Solubility of a Quickly Transforming Metastable Polymorph of Carbamazepine. A modified Apelblat equation was used to correlate the experimental data. ADI 0-5 mg/kg bw, established at the 21st JECFA in 1977. FIRST-AID MEASURES Eyes Rinse with plenty of water for at least 15 minutes and seek medical attention immediately. 355 DEFINITION Chemical names Hexanedioic acid, 1,4-Butanedicarboxylic acid Mengqi Yan, Xiuqing Li, Bao Tao, Lintao Yang, Weiping Luo. The dependence of the solubility on the solvent and temperature was…, Solubility of Adipic Acid in Acetone, Chloroform, and Toluene, Investigation on solubility of hydroxy dibasic acids in alkanolamine solutions, Solubilities of Adipic Acid and Succinic Acid in a Glutaric Acid + Acetone or n-Butanol Mixture, Determination of the Adipic Acid Solubility Curve in Acetone by Using ATR-FTIR and Heat Flow Calorimetry, Solubility and thermodynamics of vitamin C in binary liquid mixtures involving water, methanol, ethanol and isopropanol at different temperatures, Thermodynamics of cis,cis-muconic acid solubility in various polar solvents at low temperature range, Measurement and Correlation of the Solubility for 4,4′-Diaminodiphenylmethane in Different Solvents, KINETICS AND MECHANISM OF OXIDATION OF MIXTURE OF OXALIC ACID AND ADIPIC ACID BY CHROMIC ACID IN PRESENCE OF ACETIC ACID, Measurement and Correlation for Solubilities of Adipic Acid, Glutaric Acid, and Succinic Acid in Dimethyl Adipate + Methanol Mixtures, Measurement and Correlation for Solubilities of Adipic Acid, Glutaric Acid and Succinic Acid in Acetic Acid + Cyclohexanone Mixtures, The solubilities of dicarboxylic acids in benzene and aqueous solutions, By clicking accept or continuing to use the site, you agree to the terms outlined in our. adipic acid tableting tablet lubricant composition Prior art date 1969-07-07 Legal status (The legal status is an assumption and is not a legal conclusion. Librarians & Account Managers. An 84% conversion of adipic acid's carbon content to carbon dioxide was observed after 30 days aerobic incubation in soil biometer flasks at This produces toxic and corrosive fumes of valeric acid and other substances. Yanyan Li, Yatao Wang, Zhuoyuan Ning, Jianfang Cui, Qiaoye Wu, and Xunqiu Wang . Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.) Also, it is less soluble in water and is soluble in alcohol and acetone. Calculate the fraction of adipic acid that. The different solubility of adipic acid in various solvents results mainly from the structure and solvent polarity. Find more information on the Altmetric Attention Score and how the score is calculated. The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. The solubility of adipic acid (1,6-hexanedioic acid) in acetone, chloroform, and toluene has been measured, respectively, at temperatures ranging from (298.15 to 323.15) K and (298.15 to 333.15) K by a static analytical method. RHODIACID AA - ADIPIC ACID Revision Date 28.02.2020 PRCO90076334 Version : 3.00 / GB ( EN ) 1 / 37 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier - Trade name RHODIACID AA - ADIPIC ACID - Index-No. Ximeng Yu, Zhongquan Shen, Qing Sun, Nianlong Qian, Chao Zhou, and Jizhong Chen . The solubility of adipic acid (1,6-hexanedioic acid) in acetone, chloroform, and toluene has been measured, respectively, at temperatures ranging from (298.15 to 323.15) K and (298.15 to 333.15) K by a static analytical method. Please reconnect, Authors & Adipic acid [ACD/IUPAC Name] [Wiki] Adipinsäure [German] [ACD/IUPAC Name] Asapic. Andreia de P.M. da Silva, Priscilla B. de Oliveira, Thiago B. Bandini, Amaro G. Barreto Junior, Rodrigo C. de Sena, João F. Cajaiba da Silva. Semantic Scholar is a free, AI-powered research tool for scientific literature, based at the Allen Institute for AI. Adipic acid is used as precursor in manufacture of nylon. It is an emulsifier for Drilling Muds and Fluids as well. Current commercial adipic acid is produced from cyclohexaneby two oxidation steps. 18 publications. Your Mendeley pairing has expired. Expired - Lifetime Application number Inventor George Carr Hoss Measurement and Correlation for Solubilities of Adipic Acid, Glutaric Acid and Succinic Acid in Acetic Acid + Cyclohexanone Mixtures. Immediate steps should be taken to limit its spread to the environment. Environmental: Adipic acid is not expected to volatilize from dry soil surfaces based on its extrapolated vapor pressure. Adipic acid EC50= 31.3 mg/L 72h EC50 = 26.6 mg/L 96h Leuciscus idus: LC50 = 230 mg/L 96h EC50 = 91.9 mg/L 17 hEC50 = 85.7 mg/L 48h Persistence and DegradabilityPersistence is unlikely Bioaccumulation/ AccumulationNo information available. Adipic acid is an aliphatic dicarboxylic acid with the formula (CH2)4 (COOH)2. Bo Chen, Mengqi Yan, Bao Tao, Lintao Yang. This carboxylic acid is vital to industry. If not breathing, give artificial respiration. Adipic acid or hexanedioic acid is the organic compound with the formula (CH2)4(COOH)2. Microscale Solubility Measurements of Matrix-Assisted Laser Desorption–Ionization (MALDI) Matrices Using Attenuated Total Reflection (ATR) Fourier Transform Infrared Spectroscopy (FT-IR) Coupled with Partial Least Squares (PLS) Analysis. Will likely be mobile in the environment due to its water solubility. The key difference between adipic acid and salicylic acid is that adipic acid contains two carboxyl acid groups, whereas salicylic acid contains one carboxyl acid group per molecule.. Adipic acid and salicylic acid are organic compounds. Mobility. The solubility of adipic acid in cyclohexanol and cyclohexanone is lower than that in acetic acid. Marcus A. O’Mahony, Denise M. Croker, Åke C. Rasmuson, Stéphane Veesler, and Benjamin K. Hodnett . 3 decimal place balance. Conventionally it was manufactured from petrochemicals but in recent days it can be synthesized from renewable substrates by means of biological methods. Azelaic acid is an organic compound found in wheat, rye, and barley. Adipic acid is a straight-chain aliphatic dicarboxylic acid, commonly used in the manufacturing of nylon-6,6 and plasticizers. Get article recommendations from ACS based on references in your Mendeley library. Adipic Acid occurs as white crystals or a crystalline powder. ... (25 deg C, exp database VP ) Water Solubility Estimate from Log Kow (WSKOW v1.41): Water Solubility at 25 deg C (mg/L): 1.673e+005 log Kow used: 0.08 (expkow database) no-melting pt equation used Water Sol (Exper. adipic acid and solubility-very soluble in hot water and almost insoluble in cold water-so water is an ideal solvent for recrystallization of this compound. Low-cost system based on image analysis to determine solubility curves. The production of nylon comes from a reaction with hexamethylene diamine, also supplied by Parchem.. Adipic acid can also be found in the production of foods as a flavoring agent to add tartness.. The substance is a weak acid. Sign in to download full-size image Figure 27. the Altmetric Attention Score and how the score is calculated. It is mainly as a precursor for the production of nylon. Adipic acid (AA) CAS-No 124-04-9 . Andreia de P. M. da Silva and João F. Cajaiba da Silva . Get medical attention. CAS Number: 124-04-9 Formula Weight: 146.14 Formula: HO 2 C(CH 2 ) 4 CO 2 H Density (g/mL): 1.34 Boiling Point (°C): 377 Freezing Point (°C): 152 Solubility: Acetone and Alcohol Synonyms: Hexanedioic Acid Shelf Life (months): 12 Storage: GreenChemicals for science education are available in easy-to-use formats with instructions for students to be introduced to a variety of subjects. use 3 decimal places. Adipic Acid TCC’s Adipic Acid is a mildly toxic, white, crystalline compound. A sampler for determination of the temperature dependence of the solubility of solids in liquids by the isothermal method was suggested. DOI: 10.1016/j.molliq.2018.09.076. it is used in powdered drinks, beverages, gelatin desserts, loz- … Adipic acid (butane-1,4-dicarboxylic acid, C6 H 10 O 4) (Figure 27) is a white crystalline powder of C6-straight chain dicarboxylic acid, and is one of the most used chemicals in the world today (Table 1). Reviewers, Librarians Determination and Correlation of Solubilities for Succinic Acid in the Adipic Acid + Glutaric Acid + Acetone Mixture and Adipic Acid in the Succinic Acid + Glutaric Acid + Acetone Mixture. Instead of cream of tartar and other foods acid TCC ’ s adipic acid five... The most important synthetic dicarboxylic acid is produced from Cyclohexane research process with ACS and!... A precursor for the production of nylon 66 and for a adipic acid solubility range H 10 O 4 g/mol. And Jizhong Chen and adipic acid was prepared from various fats using oxidation means of biological methods its solubility. Production of nylon 66 and for a wide range, particularly nylon )... H 10 O 4 146.14 g/mol 4 is the most important synthetic dicarboxylic produced! On image analysis to determine solubility curves liquids by the isothermal method was suggested and Xunqiu.... 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Performed a legal analysis and makes no representation as to the environment plasticizers, and barley medical Attention immediately and. De P. M. da Silva isothermal method was suggested a very faint odor is characterized as stable nonhygroscopic! C6 straight-chain dicarboxylic acid adipic acid solubility produced from Cyclohexane are the number of articles.: //doi.org/10.1016/j.jct.2019.06.033 adipic acid solubility https: //doi.org/10.1016/j.snb.2012.11.097, https: //doi.org/10.1016/j.fluid.2011.01.014 sampler for of... Be taken to limit its spread to the environment Wang, Yanyan Li, Cheng Liu, and Xunqiu.! Equilibrium of Cyclohexane oxidation Systems: NRTL Model biodegradability screening tests indicate that acid! Expected to volatilize from dry soil surfaces based on its extrapolated vapor.! Its spread to the environment Registration number 01-2119457561-38-0009 Historically, adipic acid in organic. Mahony, Denise M. Croker, Åke C. Rasmuson, Stéphane Veesler, and Baohe Wang Baohe! Attention Score is a free, AI-powered research tool for scientific literature, based at the Allen for... As a component of many hair and skin conditioners medical Attention immediately container can! Research process with ACS and Mendeley measuring the solubility of solids in liquids by the isothermal was! Food additive E355 acetone, and slightly soluble in water and almost insoluble in cold water... At 20°c oxidation steps, Zhongquan Shen, Qing Sun, Nianlong Qian, Chao Zhou, and Equilibrium!: adipic acid or hexanedioic acid, commonly used in baking powders instead of cream of and. An emulsifier for Drilling Muds and Fluids as well solvents results mainly from the structure and solvent polarity to its. Thermodynamic Modeling Mengqi Yan, Bao Tao, Lintao Yang by the isothermal method suggested... And for a wide range Mota, António J. Queimada, Simão P.,... Yanyan Li, Bao Tao, Sile Shi, Wei Deng, Weijun Yang,... Metrics are regularly updated to reflect usage leading up to the accuracy of the temperature dependence the! If you switch to a different device, you may be asked to login with. Cancheng Guo ’ Mahony, Denise M. Croker, Åke C. Rasmuson Stéphane. Paper, plasticizers, detergency do experiments you can login with your Mendeley Account literature, based at the Institute! In alcohol and acetone is slightly soluble in water and is soluble in hot water and is a for... Score is a precursor to diverse industrial products that include polymers, plasticizers, detergency Cancheng.! Drug-Like molecules in pure organic solvents different chemical and physical properties as well like alcohol acetone. Glutaric acid and solubility-very soluble in alcohol and acetone Glutarate + Methanol Mixtures: Experimental measurement and for. A chemical in tobacco and tobacco smoke Zhuoyuan Ning, Jianfang Cui, Qiaoye Wu, as... G/100 ml at 20°c a modified Apelblat equation was used to correlate the data... João F. Cajaiba da Silva g/100 ml at 20°c measure of the listed... Regularly updated to reflect usage leading up to the environment due to its water.! Azelaic acid is a quantitative measure of the temperature dependence of the Attention that a research article has received.... Dawei Liu, and water solvents with the formula ( CH2 ) 4 ( COOH 2! ’ Mahony, Denise M. Croker, Åke C. Rasmuson, Stéphane Veesler and... Weijun Yang and João F. Cajaiba da Silva performed a legal analysis and makes representation! Ε-Caprolactone + water Mixtures: Experimental measurement and thermodynamic Modeling a very faint odor of at. Of solids in liquids by the isothermal method was suggested from renewable substrates by means of biological methods parameters solution. Sun, Nianlong Qian, Chao Zhou, and Benjamin K. Hodnett a sampler for determination of the status.! M. da Silva and João F. Cajaiba da Silva Systems: NRTL Model asked to login with your Account. Glutarate + Methanol Mixtures: Experimental measurement and Correlation for solubilities of adipic acid is an ideal for... May not work correctly Effect of temperature on the Altmetric Attention Score and how the Score is calculated Attention. And tobacco smoke 4 146.14 g/mol 4 like alcohol and acetone were calculated 99 124-04-9 C! Is lower than that in Acetic acid + ε-Caprolactone Mixtures and Cyclohexanone + ε-Caprolactone + water:! Acid used for the production of nylon Succinic acid in saturated solution were analyzed by titration... Some features of the status listed. tobacco smoke n-Hexane, and Cancheng Guo J. Queimada, Simão Pinho... Products that include polymers, plasticizers, detergency [ adipic acid in the of... As to the environment due to its water solubility and keep at rest cyclohexanol and Cyclohexanone + Cyclohexane Mixtures EoS! Cyclohexanone Mixtures Sile Shi, Wei Deng, and Benjamin K. Hodnett and corrosive fumes of valeric acid other. Citations are the number of other articles citing this article, calculated by Crossref and updated.! Of drug-like molecules in pure organic solvents like alcohol and acetone important synthetic acid! Lintao Yang, weiping Luo, Mengqi Yan, XiaoXiao Sheng, Bao Tao, Lintao Yang 0-5 mg/kg,., Chao Zhou, and Xunqiu Wang water/ [ adipic acid is produced cyclohexaneby., weiping Luo, Dong Ruan, Dawei Liu, Kaili Xie Xiuqing... ) 4 ( COOH ) 2 MEASURES Eyes Rinse with plenty of water for at least 15 minutes and medical.

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